Electrochemical energy storage using pseudocapacitive mode is under intense research owing to their potential in fabricating high performance renewable energy devices at a lower cost. In this paper we characterize nickel oxide (NiO) nanowires developed by electrospinning an aqueous polymeric solution containing nickel precursor for its application as a pseudocapacitors electrode. The wires are of diameter similar to 50-70 nm containing densely packed cuboidal grains (similar to 10-20 nm) with less degree of crystal defects. Electrochemical properties of the electrodes fabricated on a nickel foam substrates are evaluated by cyclic voltammetry (CV) and charge-discharge cycling (CDC), and electrochemical impedance spectroscopy (EIS) techniques. The best performing electrode showed a specific capacitance (C-s) of similar to 670 Fg(-1) with high cycling stability (similar to 100%) for over 1000 cycles and Coulombic efficiency similar to 98%. Lower electrochemical equivalent resistance (similar to 0.76 Omega), charge transfer resistance (similar to 0.45 Omega), and charge relaxation time (43 ms) are observed which are attributed to the defect free nanowire morphology that give rise to the superior performance. (C) 2014 Elsevier B.V. All rights reserved.