The mechanical durability of hydrocarbon membranes in polymer electrolyte membrane fuel cells remains insufficient. To resolve this issue, in contrast to the conventionally used method, reinforced composite membranes were fabricated by simultaneous electrospinning and spraying. A hydrophobic polysulfone (PSf) was used as a non-conducting substrate to increase the membrane's mechanical strength, and hydrophilic sulfonated poly (arylene ether sulfone) (sPAES) was used as an electrolyte. The properties and performance of a reinforced microcomposite membrane comprising electrospun PSf/sprayed sPAES were compared with those of (i) sPAES homogeneous membrane, (ii) sprayed PSf/electrospun sPAES membrane, and (iii) PSf/sPAES blend membrane. Although the electrospun PSf/sprayed sPAES membrane was slightly more durable than the others, we think that the developed membrane fabrication method holds great promise and can be further improved by utilising more compatible materials.